Technology Primer · Mass Spectrometry Imaging

MALDI MSI (Application)

With broad molecular coverage and a mature software ecosystem, MALDI MSI is the main tool for spatial proteomics and lipidomics, widely used for tumor tissue molecular classification, drug distribution, and brain and plant tissue metabolic/lipid mapping.
Table of Contents
1. Typical Applications2. Workflow and Software3. Complementarity with Matrix-Free Sources
MALDI: matrix co-crystallization + laser desorption ionization Section + matrix co-crystal Laser Desorption ionization Mass analysis Matrix absorbs laser energy and drives soft ionization of analytes; requires vacuum
MALDI MSI (Application) — schematic diagram

1. Typical Applications

MALDI imaging excels at presenting the spatial distribution of proteins, peptides, lipids and sugars at tissue scale, and is especially common for tumor boundary identification, molecular classification and candidate-drug tissue distribution. Its high throughput (fast TOF acquisition) and broad mass coverage help multi-molecule co-localization.

Common matrices differ in focus: DHB is often used for lipids and metabolites with relatively controlled background; CHCA is often used for proteins and peptides. Matrix choice needs repeated optimization based on the target molecule's mass range and background behavior.

2. Workflow and Software

The standard workflow includes frozen/paraffin sectioning, matrix spraying and co-crystallization, raster scanning acquisition, image reconstruction and statistical analysis. Software such as SCiLS Lab, MetaboScape and MSiReader is used for alignment, reconstruction and differential analysis, with imzML as the cross-platform common format.

Standardization of software and formats lets MALDI imaging results be exchanged across platforms, and also facilitates side-by-side comparison with matrix-free source data (such as LDPI), supporting multi-source complementary research.

3. Complementarity with Matrix-Free Sources

MALDI has clear advantages in broad coverage of proteins/peptides/lipids, but matrix interference in the low-mass region for small molecules makes it complementary to drug/metabolite imaging. The matrix-free ambient source (such as LDPI) exactly fills this gap.

For studies concerned with both large and small molecules, the 'MALDI + LDPI' combination is often used: the former for broad coverage, the latter for small-molecule low background, obtaining a more complete molecular picture on the same batch of samples.

Frequently Asked Questions (FAQ)

What does MALDI MSI excel at?
Spatial distribution of proteins, peptides, lipids and sugars at tissue scale, often used for tumor classification and drug distribution.
What are DHB and CHCA each suited to?
DHB is often used for lipids and metabolites with relatively controlled background; CHCA is often used for proteins and peptides.
What software is used for MALDI imaging?
SCiLS Lab, MetaboScape, MSiReader, etc.; imzML is the cross-platform common format.
How do MALDI and LDPI cooperate?
MALDI for broad coverage, LDPI for small-molecule low background; combine for a more complete molecular picture.

Get Specifications & Quotation

To obtain detailed specifications, compatible models, or a quotation for the MSI LDPI / DPI full series imaging ion sources, visit the Neo-Source official website, or contact the official team for compatibility advice tailored to your mass spectrometer (Agilent / SCIEX / Thermo and other mainstream MS).

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MALDI MSI Ion SourceMALDIDESI Mass Spectrometry Imaging (Applications)Neo-Source MSI LDPI Laser Desorption Photoionization imaging ion sourceMatrix-Free MSI Ion Source

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